61. Which of the following solution has shown the correct titration curve?
(A) NH₃
(B) CO₃ ^2-
(C) HCN
(D) PO₄^3-
(E) NaOH

57. The rest mass of an electron isWhat is the kinetic energy of an electron with the speed of 0.80c? (The constant c is the speed of light in vacuum.) (A) (B) (C) (D) (E)

58. In the hydrogen spectrum, the ratio of the wavelengths for Lyman-α radiation (n = 2 to n = 1) to Balmer-α radiation (n = 3 to n = 2) is ______. (A)(B) (C) (D) 3 (E)

59. A sample of radioactive nuclei of a certain element can decay only by γ -emission and β -emission. If the half-life for γ -emission is 24 minutes and that for β -emission is 36 minutes, the half-life for the sample is (A) 30 minutes (B) 24 minutes (C) 20.8 minutes (D) 14.4 minutes (E) 6 minutes

60. The radioactive isotope  226Ra decays to 222 Rn with a half-life of 1600 years. The radioactive isotope  238U decays to234 Th  with a half-life of 4.5× 109 years. What is the ratio of the decay rate of 1 g  226Ra to that of 10 g238 U  ? (A) 3.0 × 106 (B) 3.0 × 10-7 (C) 3.0 × 105 (D) 3.0 × 10-6 (E) 3.0 × 107

62. Cisplatin cis-[PtCl2(NH3)2] has been applied as an anti-tumor drug. What is its main interaction in vivo? (A) Binding with DNA. (B) Binding with lipid. (C) Binding with protein. (D) Binding with sugar. (E) Blocking ion absorption.

63. A chemist needs to prepare a buffered solution using one of the following acids (and its sodium salt): HA (Ka = 1.4 × 10-3 ), HB (Ka = 9.8 × 10-6 ), HC (Ka = 8.4 × 10-5 ), HD (Ka = 3.5 × 10-7 ), HE (Ka = 1.9 × 10-8 ). To prepare a solution buffered at pH = 5.10, which system will work best (a buffer with the best capacity)? (A) HA and its sodium salt (B) HB and its sodium salt (C) HC and its sodium salt (D) HD and its sodium salt (E) HE and its sodium salt

64. Of the following eleven compounds, how many of them have aromatic character? (A) 3 (B) 4 (C) 5 (D) 6 (E) 7

65. Which of the following species has the lowest dissociation energy? (A) O2 (B) O2 – (C) O2 2– (D) O2+ (E) O2 2+

66. According to the Bohr Model, please use the equation below and calculate the minimum energy required to remove the electron from a He+ ion in its first excited state. (A) 2.178 x 10-18 J (B) 5.445 x 10-19 J (C) 8.712 x 10-18 J (D) 4.356 x 10-18 J (E) 1.089 x 10-18 J

67. About the atomic orbitals, which of the following statements is incorrect? (A) In a polyelectronic atom, the orbital relative energies are E3s < E3p < E3d. (B) In H atom, energy is absorbed and electron jumps from 1s to 3s orbital. (C) The 2p orbital is spherically symmetric. (D) The square of the wave function is indicated as a probability distribution. (E) None of the above.