21. Which of the following statements is correct?
(A)
(B)
(C) One mol H₂ (at STP) has more positional probability than 1 mol H₂ at 100 K, 0.5 atm.
(D)
(E) At constant T and P, the change with ∆Η = +25 kJ, ∆S = +100 J/K, T = 300. K is not a spontaneous process.

17. Which of the following 0.10 M solutions are correctly arranged in order of most acidic to most basic? (A) HCl ＞ KCl ＞ NH4Cl ＞ KCN ＞ KOH (B) NH4Cl .＞ HCl .＞ KCl ＞ KCN ＞ KOH (C) NH4Cl .＞ HCl .＞ KCN ＞ KCl ＞ KOH (D) HCl ＞ NH4Cl ＞ KCl ＞ KCN ＞ KOH (E) HCl ＞ NH4Cl ＞ KCN ＞ KCl ＞ KOH

18. A 0.15 M solution of a weak acid is 3.0% dissociated. The Ka of the acid is calculated to be _______ . (A) (B) (C) (D)(E)

19. Two drops of indicator HIn (Ka = ), where HIn is yellow and In- is blue, are placed in 100.0 mL of 0.10 M HCl. The solution is titrated with 0.10 M NaOH. At what pH will the color change (yellow to greenish yellow) occur? (A) 7.0 (B) 8.5 (C) 9.0 (D) 7.5 (E) 8.0

20. The solubility of Fe(OH)3 () in a solution buffered at pH = 5.0 is _________ mol/L (A) (B)(C) (D) (E)

22. Consider the following reaction at 25°C: 2NO2(g)⇌N2O4(g). The values of ∆Ηο and ∆Sο are -58.03 kJ/mol and -176.6 J/K•mol, respectively. Assuming ∆Ηο and ∆Sο are temperature independent, estimate the value of K at 100.0°C. (A) 3.00 × 106 (B)(C) 8.72 (D) (E)

23. An unknown metal M is electrolyzed. It took 74.1 s for a current of 2.00 A to plate out 0.107 g of the metal from a solution containing M(NO3)3. The metal is therefore identified as _________. (A) aluminum (B) cobalt (C) bismuth (D) lead (E) gallium

24. The atomic mass of 1 H is 1.00782 amu and the mass of a neutron is 1.00866 amu. The binding energy for uranium-235 (atomic mass 235.0439 u) is calculated to be ________ J/nucleon. (A)(B) (C)(D) (E)

25. When proteins in solution are heated, the hydrogen bonds in proteins may be broken to result in collapsing of protein secondary structures. What will be the effects of the heating process on ∆H and ∆S of the proteins? (A) ∆H and ∆S all will increase. (B) ∆H and ∆S all will decrease. (C) ∆H will increase but ∆S will decrease. (D) ∆H will decrease but ∆S will increase (E) Both ∆H and ∆S will not change.

1 下列有關義齒黏著劑（denture adhesive）之敘述，何者正確？ (A) 粉狀（powder）比膏狀（cream）效果好並持久 (B)不可使用在全口義齒製作良好但有口乾症之患者 (C)粉狀比膠狀容易從義齒及口腔黏膜清除 (D)可使用在下顎全口義齒需重襯底（relining）之患者

2 上顎咬合堤（occlusion rim）大臼齒區咬合平面應離史坦生氏管（Stensen’s duct）多少吋（inch）？ (A) 1/8 (B) 1/4 (C) 1 (D) 1/2