37. In the unit cell of sphalerite, ions occupy half the tetrahedral holes in a face-centered cubic lattice of ions. What is the number of formula units of ZnS in the unit cell?
(A) 5
(B) 4
(C) 3
(D) 2
(E) 1

33. Order the following from shortest to longest bond: C2, B2, H2, N2 (A) H2, N2, C2, B2 (B) N2, C2, B2, H2 (C) C2, N2, H2, B2 (D) C2, B2, H2, N2 (E) none of these

34. Of the three cubic unit cells, which lattice packing leaves the least amount of free space in the cell? (A) simple cubic (B) body centered cubic (C) face centered cubic (D) need cell dimensions to determine this (E) hexagonal

35. A liquid placed in a closed container will cvaporate until equilibrium is reached. At equilibrium, which of the following statements is not true? (A) the partial pressure exerted by the vapor molecules is called the vapor pressure of the liquid (B) liquid molecules are still evaporating (C) the number of vapor molecules remains essentially constant (D) the boundary (meniscus) between the liquid and the vapor disappears (E) all of these statements are true

複選題36. A p-type semiconductor (A) is made by doping host atoms with atoms having more valence electrons than the host (B) is made by doping host atoms with atoms having fewer valence electrons than the host (C) has electrons that lie close in energy to the conduction bands (D) two of these (E) none of these

38. Specify the number of unpaired electrons in . (A) 0(B) 1 (C)2 (D) 4 (E) 5

39. Which of the following complexes would be diamagnetic? (A)(B)(C)(D)(E) none of these

40. For the process , what would be the ratio of cis to trans isomers in the product? (A) 1:1 (B) 1:2 (C) 1:4 (D) 4:1 (E) 2:1

41.________ isomers and ________ isomers are classes of structural isomers. (A) Geometric, optical (B) Coordination, geometric (C) Linkage, geometric (D) Coordination, linkage (E) Geometric, linkage

42. How many of the following molecules exist? I: methane, II: cycloethane, Il: isopropyne, IV: neobutane (A) 0(B) 4 (C) 2 (D) 1 (E) 3

43. The overall shape of a protein is maintained by (A) hydrogen bonding (B) ionic bonds (C) dipole-dipole bonding (D) covalent bonds (E) all of these