45. The spectrochemical series is Which of the following complexes will absorb visible radiation of the highest energy?
(A)
(B)
(C)
(D)
(E)

41. Rank the following compounds according to increasing solubility in water. I: CH3-CH2-CH2-CH3；ll: CH3-CH2-O-CH2-CH3； III: CH3-CH2-OH； IV:CH3-OH (A) I＜Il＜IV＜III (B) I ＜III＜IV＜I (C)I＜II＜III＜IV(D) III＜IV＜lI＜I (E) none is correct.

42. A liquid-liquid solution is called an ideal solution if I: it obeys PV = nRT； II: it obeys Raoult's law； IIl: solute-solute, solvent-solvent, and solute-solvent interactions are very similar； IV: solute-solute, solvent-solvent, and solute-solvent interactions are quite different. (A) II, IV (B) II, III (C) I, I (D) I, 1, 111(E) I, U, IV

43. How many unpaired electrons are found in (A) 0(B) 4 (C) 1(D) 5(E) 2

44. Which of the following statements about the complex ion Co(en)2Cl2+ (en = ethylenediamine, NH2CH2CH2NH2)is true? (A) the geometric isomers of the complex ion have identical chemical properties (B) the complex ion exhibits two geometric isomers (cis and trans) and two optical isomers (C) because en is a strong field ligand (large A), the complex ion is paramagnetic (D) the complex ion exhibits cis and trans geometric isomers, but no optical isomers (E) the complex ion contains Co(l)

46. Which of the following complexes would be diamagnetic? (A)(B) (C) (D)(E) Fel(CO)5

47. Which has the greater number of unpaired electrons? I: square planar (A) I (B) II (C) neither I nor II has any unpaired electrons (D) more information is needed (E) both I and I| have the same (nonzero) number of unpaired electrons

48. When heat is added to proteins, the hydrogen bonding in the secondary structure breaks apart. What are the algebraic signs of△H and△S for the denaturation process? (A)△H is negative and △S is positive (B) both △H and△S are negative (C) △H is positive and △S is O (D) both △H and △S are positive (E) △H is positive and△S is negative

49. Which of the following polymers is not based on a s substituted ethylene monomer? (A) polystyrene (B) Teflon (C) nylon (D) polyvinylchloride (E) polypropylene

50. Which of the following statements is/are true of alcohols? I: alcohols are characterized by the presence of the hydroxyl group (-OH)； I: the systematic name for an alcohol is obtained by replacing the final -e of the parent hydrocarbon with -oxyl； IIl: alcohols usually have much lower boiling points than might be expected from their molar masses. (A) Ill only (B) II only (C) I only (D) I and III (E) I and 2

1下列何種生長情況的改變不常見於鼻呼吸阻塞之患者？ (A)顏面高度增加 (B)垂直覆蓋增加 (C)前牙開咬 (D)上顎牙弓狹窄