70. The rate constant for a reaction increases from 10.0 s^-1 to 100.0 s^-1 when the temperature is increased from 300 K to 400 K. What is the activation energy for this reaction in kJ/mol?

(R = 8.31 J/mol·K； ln10 = 2.30)
(A) 45.6
(B) 23.0
(C) 18.3
(D) 12.7
(E) 5.0

66. Give the effusion time of 250 mL of methane through a small hole is 48 s. How long will it require for same volume of helium to pass through the same hole? (CH4=16 g/mol； He=4 g/mol) (A) 12 s (B) 24 s (C) 48 s (D) 96 s (E) 192 s

67. Given the second half-life for a second order reaction is 60 seconds. How much time is required for 87.5% reactant to be consumed in this reaction? (A) 30 seconds (B) 60 seconds (C) 90 seconds (D) 120 seconds (E) 210 seconds

68. Which of the following trends is incorrect? (A) atom size: Li ＜ Na ＜ K ＜ Cs (B) ion size: Ca2+ ＜ K+ ＜ Cl– ＜ S2– (C) electronegativity: I ＜ Br ＜ Cl ＜ F (D) boiling point: H2O ＜ H2S ＜ H2Se ＜ H2Te (E) bond angle: SbF3 ＜ AsF3 ＜ PF3 ＜ NF3

69. At 27℃, an ideal gas with a mass of 0.4 g in 100 mL has a pressure of 0.3 atm. What is the molecular weight of this gas molecule? (R = 0.082 atm·L/mol·K) (A) 328 (B) 246 (C) 133 (D) 120 (E) 30

71. Below reaction was studied at –10℃ and the following results were obtained. Considering the rate law of this reaction, what’s the unit of the rate constant? (A) (mol/L)2 ·min-1 (B) (mol/L)1 ·min-1 (C) (mol/L)0 ·min-1 (D) (mol/L)-1 ·min-1 (E) (mol/L)-2 ·min-1

72. Which of the following statements is correct? (A) Arrhenius postulated that an acid is a proton (H+) donor, and a base is a proton acceptor. (B) A buffer with a large capacity contains large volumes of the buffering components. (C) For the titrations of weak acids with strong bases, the greater pH value at the equivalence point is obtained when the stronger acid is used. (D) For a particular buffering system, all solutions that have the same ratio of [A– ]/[HA] have the same pH value. (E) An acid-base indicator can be used to determine the equivalence point of an acid-base titration because of its ability to mark the half-equivalence point of a titration by changing color.

73. At a certain temperature, placing one mole of ammonia gas into a sealed container results in 40% ammonia decomposition at equilibrium. What is the equilibrium constant KC for ammonia decomposition at that temperature? (ammonia decomposition: 2NH3(g) → N2(g) + 3H2(g)) (A) 0.043 (B) 0.12 (C) 0.80 (D) 8.33 (E) 17

74. Complete the Lewis structure for the molecular formula (C5H7ON) below. This molecule has _____ single bonds, _____ multiple bonds and ____ sp2 hybridized atoms. (A) 4, 2, 2 (B) 4, 2, 4 (C) 11, 2, 2 (D) 11, 2, 4 (E) 11, 5, 4

75. A product is electroplated by copper from CuSO4 solution. A constant current of 9.65 amp is applied by an external power supply. How long will it take to deposit 6.35 × 102 g of Cu onto the surface of product? (Cu = 63.5 g/mol) (1F = 96485 C/mol) (A) 14.22 s (B) 8.9 min (C) 2.54 h (D) 55.5 h (E) 1.37 days

76. An unknown compound is cooled at 1 atm, and it freezes at 50.0 K to form Solid I. At a lower temperature, Solid I rearranges to Solid II, which has a different crystal structure. Thermal measurements show that ΔH an ΔS for the I → II phase transition are –700.0 J/mol and –20.0 J/K mol, respectively. What is the temperature of Solids I and II in equilibrium? (A) 13.6 K (B) 19.8 K (C) 35.0 K (D) 59.8 K (E) 98.2 K