(d) Calculate the cell potential?(5pts)

(a) Write the half-cell reaction of cathode?(5pts)

(b) White the half-cell reaction of anode?(5pts)

(c) Write the reaction of electrochemical cell? (5pts)

(e) Is it an electrolytic or Galvanic cell? (5pts)

2. Describe the operational theory of glass membrane electrode. (25 pt)

3. Describe the theory of flame photometric detector and its application. (25 pt)

4. Describe the theory and application of ion pair chromatography. (25 pts)

4. A 0.611-g sample of an alloy containing Al and Mg is dissolved and treated to prevent interferences by the alloy's other constituents. Aluminum and magnesium are precipitated using 8-hydroxyquinoline, providing a mixed precipitate of Al(C9H6NO)3 and Mg(C9H6NO)2 that weighs 7.815 g. Igniting the precipitate converts it to a mixture of Al2O3 and MgO that weighs 1.002 g. Please calculate the %w/w Al and %w/w Mg in the alloy. (Al(C9H6NO)3: MW=459.45 g/mol； Mg(C9H6NO)2: MW=312.61 g/mol； Al: MW= 26.982 g/mol； Mg: MW= 24.305 g/mol； Al2O3: MW=101.96 g/mol； MgO: MW: 40.3044 g/mol)

3. The overall Kf for the complex ion is 1.7 × 107. Ksp for AgI is 1.5 × . What is the molar solubility of AgI in a solution that is 2.0 M in NH3?

2. Titrating 30.00 mL of a saturated calcium iodate solution requires 28.91 mL of a 0.092 M solution of Na2S2O3. Calculate Ksp for Ca(IO3)2, according to the equation 

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