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研究所、轉學考(插大)-分析化學
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110年 - 110 國立臺灣大學_碩士班招生考試_部分系所:(共同科目)分析化學(A)#100459
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題組內容
3. Describe the fundamental concept of chromatography. Also, define the following terms for a separation column with a length L: (20%)
(d) height equivalent of theoretical plate (HETP)
其他申論題
2. If the above carbonate system exists in a high saline medium (for example, seawater), the apparent dissolution constants will shift to pk1'=6.0 and pK2 =9.2. Try to use concepts related to ionic strength and activity to explain the so-calied "pKa-shifting" phenomenon. (20%)
#420383
(a) partition coefficient k'
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(b) retention time ta
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(c) flow speed u and migration speed um
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4. What is ICP-MASS? Brief describe its principle (you may draw diagrams to make it clear). Give some examples to show its application to environmental or clinic chemistry. (20%)
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5. Mercury is toxic element. The determination of mercury is largely depending upon a technique called "cold-vapor atomic absorption spectrometry". Use illustrations to describe this technique. (20%)
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6. Testing drivers' alcohol is an obligation should any traffic accident take place. What is the method to measure alcohol in driver's breath? If the driver refuses to take breath test, how can we measure alcohol in his blood? (20%)
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1. 如圖,在△ABC中,為∠BAC的角平分線,試證: 。
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(1) 假設對所有的正整數n,。試證:對所有的正整數均成立。
#420392
(2) 試舉出數列滿足,且。
#420393