試卷名稱:112年 - 112 台灣聯合大學系統_碩士班招生考試_化學類:無機化學#117893
年份:112年
科目:研究所、轉學考(插大)◆無機化學
14. In neutral aqueous solution,E°for the Mn3+/Mn2+ couple is +1.54 V. At pH 14,E°for the Mn(OH)3/Mn(OH)2 couple is t0.15 V. Which of the following statements is incorrect?
(A) At pH 14, Mn(II) and Mn(III) both precipitate from aqueous solution as hydroxides
(B) Mn(III) is less stable with respect to reduction to Mn(II) at pH 14 than at pH 7
(C) The Mn(OH)3/Mn(OH)2 couple refers to an equilibrium involving Mn(III) and Mn(II)
(D) At pH 7, Mn3+(aq) is a relatively strong oxidizing agent