22. Based on reaction shown as below, the two complexes can be classified into which type of isomerism?

(A) stereoisomerism
(B) optical isomerism
(C) geometric isomerism
(D) ionization isomerism
(E) linkage isomerism

18. Determine Lewis base strength in the gas phase of following amines: (A) NMe3 ＞ NH2Me ＞ NH3 (B) NH2Me ＞ NMe3 ＞ NH3 (C) NH3 ＞ NMe3 ＞ NH2Me (D) NH3 ＞ NH2Me ＞ NMe3 (E) None of the above.

19. Using the data below, calculate the normal boiling point of liquid A at 1 atm, A(liquid) → A(gas): the ΔH° = 25.0 kJ/mol and the ΔS° = 50.0 JK−1mol−1 (A) 50 K (B) 200 K (C) 227 K (D) 323 K (E) 500 K

20. Which of the followings octahedral complexes will not form precipitate of AgI at once after the aqueous AgNO3 is added? (A) Co(NH3)6I3 (B) Pt(NH3)4I4 (C) Na2PtI6 (D) Cr(NH3)4I3 (E) All of them will form AgI precipitate.

21. How to make a p-type semiconductor? (A) Dope host atoms (Si) with atoms having fewer valence electrons than the host, such as B. (B) Dope host atoms (As) with atoms having fewer valence electrons than the host, such as Se. (C) Dope host atoms (Si) with atoms having more valence electrons than the host, such as As. (D) Dope host atoms (As) with atoms having more valence electrons than the host, such as Ge. (E) None of the above.

23. What is the product called after glycine and alanine undergo condensation reactions? (A) ester (B) dipeptide (C) DNA (D) polysaccharides (E) None of the above.

24. Which compound does not possess a sp2 hybridized orbital? (A) 2-butanone (B) aspirin (C) acetic anhydride (D) 2-propanol (E) aniline

25. Consider the following orderings. Which of these gives a correct trend in ionization energy?I Be ＜ Mg ＜ Ca ＜ SrII Cl ＜ Si ＜ P ＜ AlIII F ＜ Cl ＜ Br ＜ IIV Na+ ＜ Mg2+ ＜ Al3+ ＜ Si4+ (A) I (B) II (C) III (D) IV (E) None of the above.

26. What is the correct order of the following bonds in terms of increasing polarity? (A) N-Cl, P-Cl, As-Cl (B) P-Cl, N-Cl, As-Cl (C) As-Cl, N-Cl, P-Cl (D) P-Cl, As-Cl, N-Cl (E) As-Cl, P-Cl, N-Cl

27. Which of the following electron configurations is incorrect? (A)S2– : 1s22s22p63s23p6(B) Na+:1s2 2s 2 2p6(C) Ga: 1s2 2s2 2p63s23p64s23d10(D)V:1s22s22p63s23p64s23d3(E)I: 1s22s22p63s23p64s2 3d104p65s24d105p5

28. How many moles of Ca(NO3)2 must be added to 0.5 L of a 0.4 M KF solution to begin precipitation of CaF2? For CaF2, Ksp = 4.0 ✖ 10–11.(A) 2.0 ✖ 10–12(B) 1.0 ✖ 10–10 (C) 2.0 ✖10–10(D)1.0 ✖ 10–9(E) 5.0 ✖10–9