57. Which orbital diagram violates the rule "no two electrons can have the same set of four identical quantum numbers"?
(A)
(B)
(C)
(D)
(E)

53. Salt A and salt B were dissolved separately in 100 mL beakers of water. The water temperatures were measured and recorded as shown in the table below: Salt A: initial water temp. 25.1°C final water temp. 30.2°C Salt B: initial water temp. 25.1°C final water temp. 20.0°C Which statement is a CORRECT interpretation of these data? (A) The dissolving of only salt A was endothermic. (B) The dissolving of only salt B was exothermic. (C) The dissolving of both salt A and salt B was endothermic. (D) The dissolving of salt A was exothermic and the dissolving of salt B was endothermic. (E) The dissolving of both salt A and salt B was endothermic.

54. How many moles of oxygen gas, O2, will react with 2 moles of nitrogen monoxide gas, NO, according to the following equation? ___ NO (g) + ___ O2(g) ____ NO2(g) [O2 = 32.00 g/mol; NO = 30.01; NO2 = 46.01] (A) 1 mol (B) 2 mol (C) 3 mol (D) 4 mol (E) none of the above

55. Which pair of Lewis electron-dot symbols correctly depicts the elements: boron and carbon? (A) (B) (C) (D) (E)

56. Which pair of words correctly completes this statement: Ultraviolet light is more dangerous than infrared light because it has more energy. The _______________ of ultraviolet light is _____________ than infrared light. (A) wavelength – longer (B) frequency – higher (C) speed – greater (D) speed – less (E) frequency – lower

58. Which of the following plots correctly describe ideal gas behavior? (A)①②③ (B) only① and② (C) only① and③ (D) only② and③ (E) only①

59. These compounds are: (A) enantiomers (B) diasteroisomers (C) conformers (D) geometrical isomers (E) identical

60. Rank the following molecules in order of decreasing C-C bond length of their shortest C-C bonds. ① benzene ② 1,3-butadiene (CH2CHCHCH2) ③ 1,2-propadiene (CH2CCH2) ④ethyne (HCCH) (A) ① ＞ ②＞ ③ ＞④ (B) ④＞ ③＞ ②＞ ①(C) ③＞ ②＞ ④ ＞ ① (D) ①＞ ③＞ ② ＞ ④ (E) ④＞ ② ＞ ③＞ ① 

II. Choose one correct answer for the following questions61. Which one is CORRECT for buffer capacity of a solution? (A) It is defined as the number of moles of a strong acid or a strong base that cause 1 mL of the buffer to undergo a 1.00-unit change in pH. (B) It depends only on the total concentration of buffers, not on their concentration ratio. (C) The pKa of the acid chosen for a given application should lie within ± 1 unit of the desired pH for the buffer. (D) A buffer solution of any desired pH can be prepared by combining calculated quantities of buffer pair, no need any adjustment. (E) Dissociation constants would not interfere with the predicted pH values.

62. There is a titration of 50.00 mL of 0.0500 M Fe2+ with 0.1000 M Ce4+ in a medium (1.0 M H2SO4). Calculate the potential after the addition of 25.00 mL of Ce4+. Ce4+ + e- → Ce3+      Eo = 1.44 V (1 M H2SO4) Fe3+ + e- → Fe2+       Eo = 0.68 V (1 M H2SO4) (A) 0.64 V (B) 1.06 V (C) 1.56 V (D) 2.01 V (E) 2.21 V

63. What mass of Ba(IO3)2 (487 g/mol) (Ksp = 1.57 × 10-9) can be dissolved in 400.0 mL of water at 25℃? (A) 0.732 mg (B) 5.45 mg (C) 0.142 g (D) 0.178 g (E) 0.280 g