題組內容

27. (14 points) The complex trans-PtCl₂(pip)₂ (pip = piperidine) reacts with NaNO₂ in methanol to form trans-PtCl(NO₂)(pip)₂. The kinetic data for a reaction between a 0.0007 M solution of trans-PtCl₂(pip)₂ and different concentrations of NaNO₂ are given below. The reaction follows the rate law:

(3) (4 points) Plot a graph of [NaNO₂] (x-axis) against kobs (y-axis) and use this to calculate k₁ and k₂.