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110年 - 110 國立中央大學_碩士班招生考試_化學工程與材料工程學系/甲組(一般生):化工熱力學及化學反應工程#105938
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3. For the steady-state, adiabatic, irreversible flow of an incompressible liquid in a horizontal pipe of constant cross-sectional area, show that:
(b) (5%) The temperature increases in the direction of flow, and
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(a) (18%) Derive a rate law for the deposition of TiO2
#451903
(b) (8%) The experimental results show that at 200℃ the reaction is second order at low partial pressure of TTIP and zero order at high partial pressures. While at higher temperature (300 ℃ ) the reaction is second order in TTIP over the entire pressure range. Discuss these results based on the rate law derived above. [Hint: adsorption is exothermic in general]
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2. (10%) The intensive state of a PVT system containing N chemical species andπ phases is in equilibrium. Show that the phase rule is: F = 2 - π + N, where F is the degree of freedom of the system.
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(a) (5%) The velocity is constant,
#451906
(c) (5%)The pressure decreases in the direction of flow (Hint: is defined as the volume expansivity and Cp is the heat capacity at constant pressure).
#451908
(a) (6%) Calculate the composition of the vapor in equilibrium with a liquid containing 60 mol % perfluoro-n-heptane and 40 mol % of n-heptane at 25℃ and 0.6 bar, assuming the solution is ideal.
#451909
(b) (10%) Please derive the expressions of the activity coefficient for both components in a binary mixture, assuming the solution obeys the regular solution theory. The excess Gibbs energy equation of the regular solution theory is as following:, where δi is solubility parameter of component i and Φi is volume fraction of component i:
#451910
(c) (6%) Recalculate the composition in part (a), assuming the solution obeys the regular solution theory. The regular solution parameters are
#451911
(d) (3%) Which model (ideal solution or regular solution) provides better estimation of gas phase compositions? Please give the reason according to the gas phase composition results in (a) and (c).
#451912
五、在液態光化學反應A→B中,A之起始濃度為12mol/L,反3鐘後 的濃度為0.72mol/L,請列出此反應的速率方程式?請注意!必須寫明單位才給分。
#441996
相關試卷
110年 - 110 國立中央大學_碩士班招生考試_化學工程與材料工程學系/甲組(一般生):化工熱力學及化學反應工程#105938
110年 · #105938
110年 - 110 高雄科技大學_碩士班招生考試_化學工程與材料工程系:化學反應工程(甲組)#104403
110年 · #104403