(b) Draw each SALC and give it a symmetry label. Assume that PPh3 is a pure σ donor. Provide an appropriate label for each molecular orbital, sketch each molecular orbital, and fill in the correct number of electrons. (4%)

21. Consider the octahedral vanadyl ion, VO(H2O)5^2+: (15%) (a) First, construct the molecular orbital diagram of square pyramidal V(H2O)5^4+. Assume that H2O is a pure σ donor. Provide an appropriate label for each molecular orbital, sketch each molecular orbital, and fill in the correct number of electrons. (6%)

(b) Draw each SALC and give it a symmetry label. Assume that PPh3 is a pure σ donor. Provide an appropriate label for each molecular orbital, sketch each molecular orbital, and fill in the correct number of electrons. (4%)

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