71. The following substrate is a starting material in the synthesis of compounds having opioid activity. Show all products that would result from the reaction below.
(A) I, II, III
(B) I, III, IV
(C) I, III, V
(D) II, III, IV
(E) II, IV, V

67. This cyclic carbocation has two sets of degenerate pi-molecular orbitals. Choose the correct order MO, s energies for this system? (A) V = I ＜ IV ＜ III = II (B) V ＜ IV = II ＜ I = III (C) III = II ＜ I = IV ＜ V (D) III = IV ＜ II ＜ I = V (E) V ＜ I = IV ＜ II = III

68. What product would be obtained for the following reaction? . (A) (B) (C) (D) (E)None of the above

69. When 1-methyl-1-cyclohexene is respectively treated with the following reagent set, which will give the same product? (A) II, V (B) III, IV (C) II, III, V (D) I, V (E) I, III

70. Predict the outcome of the following sequence of reactions. (A) (B) (C) (D) (E)

72. Predict the structure of the hydrolysis product. (A) (B) (C) (D) (E)

73. In order to synthesize the final product shown below, predict when should a protecting group be added and when should it be removed? (A) The hydroxyl group should be protected before step I and removed after step I (B) The hydroxyl group should be protected before step I and removed after step II (C) The hydroxyl group should be protected before step I and removed after step III (D) The hydroxyl group should be protected before step II and removed after step III (E) There is no need for a protecting group in this synthesis.

74. Which of the following Diels-Alder reactions has the largest reaction rate constant? (A) (B) (C) (D) (E)

75. What is the product of this reaction? ?(A) (B) (C) (D) (E)

76. What is the major product obtained from the following reaction sequence? (A) (B) (C) (D) (E)

77. What is the major product of the following reaction? (A) (B) (C) (D) (E)